Addition polymerisation

• Addition polymerisation?is one of the most important addition reactions of alkenes which form the basis of the plastics industry
• Addition polymerisation is the reaction in which many?monomers?containing at least one C=C double bond form long chains of?polymers?as the only product
  • Just like in other addition reactions of alkenes, the π-bond in each C-C bond breaks and then the monomers link together to form new C-C single bonds

   

• A?polymer?is a long-chain molecule that is made up of many repeating units
• The small, reactive molecules that join together to form the polymer are called?monomers
• A polymerisation reaction can be represented by a?general formula?or by using?displayed formulae
  • Eg. poly(ethene) and poly(chloroethene) (also known as?PVC) are polymers made up of the ethene and chloroethene monomers respectively and are commonly used in making plastics

   

The general formulae of the addition polymerisation of ethene (1) and chloroethene (2)

The displayed formulae of the addition polymerisation of ethene (1) and chloroethene (2)

• Just like any other?addition?reaction of alkenes, addition polymerisation gives only?one?product

Deducing repeat units

• A?repeat unit?is the smallest group of atoms that when connected one after the other make up the polymer chain
  • It is represented by?square brackets?in the displayed and general formula

   

• In?poly(alkenes)?(such as poly(ethene)) and?substituted poly(alkenes)?(such as PVC) made of?one type of monomer?the repeating unit is the same as the monomer except that the C=C double bond is changed to a C-C single bond

The repeating units of poly(ethene) and poly(chloroethene) are similar to their monomer except that the C=C bond has changed into a C-C bond

Answer 1:

• • When ethenol, CH(OH)=CH2, is polymerised, the C=C double bond opens to produce a repeating unit of -CH(OH)-CH2- This gives the polymer poly(ethenol)

   

Answer 2:

• • To find the monomer, first the repeating unit should be deduced. Repeating units have only 2 carbons in the polymer main chain

   

• • Since the repeating unit is now found, it can be concluded that the monomer is prop-2-enoic acid

   

Answer 3:

• • Again, the repeating unit only has 2 carbons in the polymer chain which in this case are two carbon atoms that each contain one OH group
  • Thus, when ethene-1,2-diol, CH(OH)=CH(OH), is polymerised, the C=C double bond opens to produce a repeating unit of? -CH(OH)-CH(OH)- which gives the polymer poly(ethene-1,2-diol)