Concentration

• The more?concentrated?a solution is, the?greater?the number of?particles?in a given volume of solvent
• An increase in?concentration?causes in an increased?collision frequency?and therefore an increased?rate of reaction

The diagram shows a higher concentration of particles in (b) which means that there are more particles present in the same volume than (a) so the chances and frequency of collisions between reacting particles is increased causing an increased rate of reaction

Pressure

• An increase in pressure in reactions that involve gases has the same effect as an increased concentration of solutions
• When the?pressure?is increased, the molecules have less space in which they can move
• This means that the number of?effective collisions?increases due to an increased?collision frequency
• An increase in pressure therefore increases the?rate of reaction

The diagram shows a higher pressure in (b) which means that the same number of particles occupy a smaller volume, resulting in an increased collision frequency and therefore increased rate of reaction

Temperature

• Increasing the temperature of the reaction mixture increases the?rate of reaction?in the following two ways:
  • At higher temperatures, the particles are moving faster, so collide more frequently. A higher number of collisions in total mean a higher?number?of successful collisions
  • At higher temperatures, a higher proportion of the molecules have the activation energy or more. This means that a higher?proportion?of collisions are?successful

An increase in temperature causes an increase in the kinetic energy of the particles. The number of collisions increases and the proportion of successful collisions increases?

Particle Size

• Only the particles on the surface of a solid will collide with particles of the other reactant
• If the surface area is increased, more particles will be on the surface and able to collide with particles of the other reactant
  • This means that there will be more collisions in total and therefore more?successful?collisions.
• Surface area?can be increased by?decreasing the size?of the reactant particles
  • For example, powders have a very large?surface area

An increase in surface area of a solid reactant allows more particles to come into contact with each other

Answer:

The correct option is?A.

• • Increasing pressure and raising temperature increases the number of successful collisions
  • Increasing the particle size decreases the surface area and reduces the number of collisions