The?molecular?formula?is the formula that shows the?number?and?type?of each atom in a molecule
E.g. the molecular formula of ethanoic acid is C2H4O2
The?empirical?formula?is the simplest whole number ratio of the atoms of each element present in one molecule or formula unit of the compound
E.g. the empirical formula of ethanoic acid is CH2O
Organic molecules?often have?different?empirical and molecular formulae
The formula of an?ionic?compound?is always an?empirical formula
Empirical Formula Calculations
Empirical formula
The?empirical formula?is the?simplest whole number ratio?of the atoms of each element present in one molecule or formula unit of the compound
It is calculated from a knowledge of the masses of each element in a sample of the compound
It can also be deduced from data that give the?percentage composition by mass?of the elements in a compound
Worked Example
Determine the empirical formula of a compound that contains 10 g of hydrogen and 80 g of oxygen
Answer:
Worked Example
Determine the empirical formula of a compound that contains 85.7% carbon and 14.3% hydrogen
Answer:
Molecular formula
The?molecular formula?gives the actual numbers of each element present in the formula of the compound
The molecular formula can be found by dividing the?relative?molecular massby the?relative mass?of the?empirical formula?and finding the multiple that links the empirical formula to the molecular formula
Multiply?the empirical formula by this number to find the molecular formula
Worked Example
The empirical formula of X is C4H10S and the relative molecular mass of X is 180.42. What is the molecular formula of X??Relative Atomic Mass ?? Carbon: 12.01??? Hydrogen: 1.01? ? Sulfur: 32.07
Answer:
Step 1:?Calculate the relative mass of empirical formula
Relative empirical mass = (C x 4) + (H x 10) + (S x 1)
Relative empirical mass = (12.01 x 4) + (1.01 x 10) + (32.07 x 1)
Relative formula mass = 90.21
Step 2:?Divide relative molecular mass of?X?by relative mass of empirical formula
The multiple between X and the empirical formula = 180.42/90.21 = 2