When two atoms in a covalent bond have the?same electronegativity?the covalent bond is?nonpolar
The two chlorine atoms have identical electronegativities so the bonding electrons are shared equally between the two atoms
When two atoms in a covalent bond have?different electronegativities?the covalent bond is?polar?and the electrons will be drawn towards the?more electronegative?atom
As a result of this:
The negative charge centre and positive charge centre do not?coincide?with each other
This means that the?electron distribution?is?asymmetric
The?less?electronegative?atom gets a partial charge of?δ+?(delta?positive)
The?more?electronegative?atom gets a partial charge of?δ-?(delta?negative)
The greater the difference in?electronegativity?the more polar the bond becomes
Cl has a greater electronegativity than H causing the electrons to be more attracted towards the Cl atom which becomes delta negative and the H delta positive
Dipole moment
The?dipole moment?is a measure of how?polar?a bond is
The?direction?of the dipole moment is shown by the following sign in which the?arrow?points to the?partially negatively charged end?of the dipole:
The sign shows the direction of the dipole moment and the arrow points to the delta negative end of the dipole
Worked Example
The electronegativity values of four elements are given.
C = 2.6? ? ? ? N = 3.0? ? ? ?O = 3.4? ? ? ?F = 4.0
What is the order of?increasing?polarity of the?bonds in the following compounds?A. CO < OF2?< NO < CF4
B. NO < OF2?< CO < CF4
C. CF4?< CO < OF2?< NO
D. CF4?< NO < OF2?< CO
Answer:
The correct option is?B.
You have to calculate the difference in electronegativity for the bonds and then rank them from smallest to largest:
NO? (3.4 - 3.0 =?0.4)
OF2?(4.0 - 3.4 =?0.6)
CO? ?(3.4 - 2.6 =?0.8)
CF4? (4.0 - 2.6 =?1.4)
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