Making Esters

• Alcohols and carboxylic acids react to make esters in?esterification?reactions
• Esters are compounds with the functional group R-COO-R
• Esters are sweet-smelling oily liquids used in food flavourings and perfumes
• Ethanoic acid will react with ethanol in the presence of concentrated sulfuric acid (catalyst) to form ethyl ethanoate:

CH₃COOH + C₂H₅OH → CH₃COOC₂H₅?+ H₂O

Diagram showing the formation of ethyl ethanoate

Naming Esters

• An ester is made from an alcohol and carboxylic acid
• The first part of the name indicates the length of the carbon chain in the alcohol, and it ends with the letters ‘- yl’
• The second part of the name indicates the length of the carbon chain in the carboxylic acid, and it ends with the letters ‘- oate’
• e.g. the ester formed from?pentanol and?butanoic acid is called?pentyl?butanoate

Diagram showing the origin of each carbon chain in ester

• Some examples of common esters:

Examples of Esters Table